越冬浮游植物光合作用活性的原位研究   总被引：7，自引：3，他引：7       下载免费PDF全文

吴晓东  孔繁翔  曹焕生  张民  刘桂民  赵巧华 《湖泊科学》2007,19(2):139-145

水体中浮游植物在越冬期间数量少,关于湖泊中越冬浮游植物如蓝藻、绿藻、硅藻等浮游植物的光合作用活性情况少见报道.本实验通过Phyto-PAM(Pulse Amplitude Modulation)对最大光量子产量Fv/Fm(可变荧光和最大荧光之比)和快速光曲线的测定,结合显微镜镜检结果,并在室内进行了硫酸铜处理以及鲁哥氏液处理实验,对太湖、巢湖和玄武湖处于越冬期间的浮游植物进行了原位光合作用活性的研究.显微镜镜检结果表明太湖和玄武湖水体中以绿藻和硅藻为主,而蓝藻很少,巢湖水体中有大量蓝藻、绿藻和硅藻.Phyto-PAM在对玄武湖和太湖水样原位测定时未检测出蓝藻,而绿藻和硅藻有光合作用活性,其Fv/Fm在0.5左右;对巢湖的水体检测到的蓝藻、绿藻、硅藻都具有光合作用活性,其中绿藻和硅藻的Fv/Fm在0.5左右,蓝藻的Fv/Fm在0.3左右;用硫酸铜处理实验在巢湖水样中发现水体仅有硅藻活性(Fv/Fm下降至0.2左右),而用鲁哥氏液处理后无任何藻类光合作用活性.上述实验结果表明,即使处于越冬期间,以较多数量出现在水体中的蓝藻、绿藻和硅藻仍然具有较高的光合作用活性.  相似文献   

应用查表法模拟区域对流层O3、Nox分布和演化的研究   总被引：2，自引：0，他引：2  

朱彬  肖辉  黄美元  李子华 《大气科学》2001,25(1):49-60

应用STEM-II气相光化学模式探讨了影响对流层O3、NOx气相光化学转化率的各物理、化学因子。表明在我国多数地区光化学污染物特征(NMHC/NOx较高)下,光辐射强度、温度、初始O3浓度和NOx浓度是影响O3、NOx气相光化学转化率的主要因子。将以上因子分档组合,计算并建立了各种情况下O3、NOx气相光化学转化率的查算表,并将之用于模拟区域O3、NOx的演化和分布。结果表明,与光化学模式直接耦合计算法相比,该方法既能显著缩短计算时间,又能基本反映大气化学反应的非线性过程,并与直接耦合法符合得较好。  相似文献   

Sensitivity Analysis of Photochemical Indicators for O<Subscript>3</Subscript> Chemistry Using Automatic Differentiation     

Yang?ZhangEmail author  Christian?H.?Bischof  Richard?C.?Easter  Po-Ting?Wu 《Journal of Atmospheric Chemistry》2005,51(1):1-41

Photochemical indicators for determination of O₃–NO_x–ROG sensitivity and their sensitivity to model parameters are studied for a variety of polluted conditions using a comprehensive mixed-phase chemistry box model and the novel automatic differentiation ADIFOR tool. The main chemical reaction pathways in all phases, interfacial mass transfer processes, and ambient physical parameters that affect the indicators are identified and analyzed. Condensed mixed-phase chemical mechanisms are derived from the sensitivity analysis.Our results show that cloud chemistry has a significant impact on the indicators and their sensitivities, particularly on those involving H₂O₂, HNO₃, HCHO, and NO_z. Caution should be taken when applying the established threshold values of indicators in regions with large cloud coverage. Among the commonly used indicators, NO_y and O₃/NO_y are relatively insensitive to most model parameters, whereas indicators involving H₂O₂, HNO₃, HCHO, and NO_z are highly sensitive to changes in initial species concentrations, reaction rate constants, equilibrium constants, temperature, relative humidity, cloud droplet size, and cloud water content.  相似文献   

Interpretation of Mid-Stratospheric Arctic Ozone Measurements Using a Photochemical Box-Model     

Sinnhuber  B.-M.  Müller  R.  Langer  J.  Bovensmann  H.  Eyring  V.  Klein  U.  Trentmann  J.  Burrows  J. P.  Künzi  K. F. 《Journal of Atmospheric Chemistry》1999,34(3):281-290

In this study measurements of mid-stratospheric Arctic ozone are compared with model simulations. The measurements obtained at Spitsbergen (79°N, 12°E) by ground based millimeter-wave radiometry exhibit large day to day variabilities as well as periods with low ozone. To interpret these measurements, calculations were made using the new photochemical box-trajectory model BRAPHO, with air parcel trajectories calculated from analyzed wind fields. Using a relatively simple approach, the model reproduces the observed ozone variability well, including inter-annual variations. The explanation for the observed ozone behavior is that at these altitudes ozone is determined by what we call dynamically controlled photochemistry. This means that the photochemical evolution of the ozone volume mixing ratio is mainly controlled by the atmospheric dynamics, in particular the solar zenith angle the air parcel has experienced.  相似文献   

利用光化学反射植被指数估算光能利用率研究的进展   总被引：1，自引：0，他引：1  

陈晋  唐艳鸿  陈学泓  杨伟 《遥感学报》2008,12(2):331-337

植被光能利用率(LUE)是估计植被初级生产力(GPP)和净初级生产力(NPP)模型的一个重要输入,准确地估计LUE对于生态学研究有重要的意义.由于LUE随环境的变化关系十分复杂,现有的LUE估算模型过于粗糙简单,而通过遥感直接估计LUE将会更加可靠.研究表明,光化学反射植被指数(PRI)与LUE有很好的相关性,故PRI在利用遥感估计LUE方面具有极大的潜力.但是很多研究也发现了PRI-LUE的关系不够稳健,受许多因素的干扰,比如物种构成、冠层结构及大气等.因此,PRI的广泛应用还需要更多的研究.本文首先介绍了PRI的定义及PRI随LUE变化的生理机制,再综述了一些利用遥感手段建立PRI-LUE关系的例子,然后分析了影响PRI-LUE关系的各种干扰因素,最后对PRI研究取得的成果、存在的问题以及发展前景作了总结.  相似文献   

Archean Mass-independent Fractionation of Sulfur Isotope:New Evidence of Bedded Sulfide Deposits in the Yanlingguan-Shihezhuang area of Xintai, Shandong Province     

LI Yanhe  HOU Kejun  WAN Defang  YUE Guoliang 《《地质学报》英文版》2008,82(2):444-450

Multiple sulfur isotope ratios （^34S/^33S/^32S） of Archean bedded sulfides deposits were measured in the Yanlingguan Formation of the Taishan Group in Xintai, Shandong Province, East of China; 633S = -0.7%o to 3.8‰,δ^34S = 0.1‰-8.8‰, △^33S = -2.3‰ to -0.7‰. The sulfur isotope compositions show obvious mass-independent fractionation （MIF） signatures. The presence of MIF of sulfur isotope in Archean sulfides indicates that the sulfur was from products of photochemical reactions of volcanic SO2 induced by solar UV radiation, implying that the ozone shield was not formed in atmosphere at that time, and the oxygen level was less than 10-5 PAL （the present atmosphere level）. The sulfate produced by photolysis of SO2 with negative △^33S precipitated near the volcanic activity center; and the product of element S with positive △^33S precipitated far away from the volcanic activity center. The lower △^33S values of sulfide （-2.30‰ to --0.25‰） show that Shihezhuang was near the volcanic center, and sulfur was mostly from sulfate produced by photolysis. The higher △^33S values （-0.5‰ to -‰） indicate that Yanlingguan was far away from the volcanic center and that some of sulfur were from sulfate, another from element S produced by photolysis. The data points of sulfur isotope from Yanlingguan are in a line parallel to MFL （mass dependent fractionation line） on the plot of δ^34S--δ^33S, showing that the volcanic sulfur species went through the atmospheric cycle into the ocean, and then mass dependent fractionation occurred during deposition of sulfide. The data points of sulfur isotope from Shihezhuang represent a mix of different sulfur source.  相似文献   

基于活力特征分析的城市安置社区公共空间研究——以苏州城区6个安置社区为例   总被引：2，自引：1，他引：1  

王勇  邹晴晴  李广斌 《地理科学》2018,38(5):747-754

由“散居”到“集居”,安置社区面临社会关系重建的巨大压力。基于公共空间活力内涵,采用AHP-模糊综合评价法,构建了城市安置社区公共空间活力评价模型,以苏州市6个安置社区为例,对3种安置模式的社区公共空间活力特征进行定量评价和比较。发现：① 不同安置模式的社区公共空间活力存在明显差异。尽管异地安置社区的公共空间的设施完备、类型多样,但是其公共空间的社会活力度最低。对于公共空间活力提升,社区公共空间背后的社会属性比其物质属性更为重要。②公共空间因子活力度与关注度存在不匹配现象。基于“社会-空间”辩证互动逻辑,提出安置社区公共空间活力营造策略： 对于今后安置社区,适宜“村内小集居+跨村大聚居”的安置模式,通过最大程度维系原有“熟人社区”群体的社会边界,提升公共空间活力,减轻社区社会关系重建的压力;对于现有安置社区,可根据公共空间因子活力度和关注度的匹配关系,划分公共空间改造的优先级,采用差别化的改造策略,提升公共空间活力及其改造资金的使用效率。  相似文献   

南京及周边黑碳气溶胶对臭氧影响的观测分析和数值模拟          下载免费PDF全文

朱彬  智利蓉  卢文  高晋徽  侯雪伟 《大气科学学报》2021,44(4):626-635

利用南京地面站点2016—2017年黑碳气溶胶(Black Carbon, BC)和臭氧(O_3)逐小时观测资料,对比分析了不同季节BC与近地面O_3的关系。结果表明,高BC(高于平均值)影响下的O_3质量浓度值明显比低BC(低于平均值)影响下的O_3质量浓度值低,这种抑制作用在秋冬季明显高于春夏季,且BC与O_3的负相关性在秋冬季显著高于春夏季,而PM_(2.5)与O_3的负相关性不显著。利用WRF-Chem模式,对2017年12月个例开展BC反馈效应对O_3影响的数值模拟,结果再次证实BC对O_3存在负反馈影响。其影响机制是:BC可通过抑制边界层发展,使近地面NO_x积聚,从而减少臭氧的化学生成(VOCs控制区);BC可通过抑制边界层垂直湍流交换,减少边界层上部高O_3向下的湍流输送,从而减少近地面O_3;BC可通过减小近地面风速,减少O_3的平流输入,从而减少地面O_3。不同个例的主要控制因子不同。  相似文献   

Spatial and Temporal Distributions and Sources of Anthropogenic NMVOCs in the Atmosphere of China: A Review     

Fanglin WANG  Wei DU  Shaojun LV  Zhijian DING  Gehui WANG 《大气科学进展》2021,38(7):1085-1100

As the key precursors of O_3, anthropogenic non-methane volatile organic compounds(NMVOCs) have been studied intensively. This paper performed a meta-analysis on the spatial and temporal variations of NMVOCs, their roles in photochemical reactions, and their sources in China, based on published research. The results showed that both nonmethane hydrocarbons(NMHCs) and oxygenated VOCs(OVOCs) in China have higher mixing ratios in the eastern developed cities compared to those in the central and western areas. Alkanes are the most abundant NMHCs species in all reported sites while formaldehyde is the most abundant among the OVOCs. OVOCs have the highest mixing ratios in summer and the lowest in winter, which is opposite to NMHCs. Among all NMVOCs, the top eight species account for 50%-70% of the total ozone formation potential(OFP) with different compositions and contributions in different areas. In devolved regions, OFP-NMHCs are the highest in winter while OFP-OVOCs are the highest in summer. Based on positive matrix factorization(PMF) analysis, vehicle exhaust, industrial emissions, and solvent usage in China are the main sources for NMHCs. However, the emission trend analysis showed that solvent usage and industrial emissions will exceed vehicle exhaust and become the two major sources of NMVOCs in near future. Based on the meta-analysis conducted in this work,we believe that the spatio-temporal variations and oxidation mechanisms of atmospheric OVOCs, as well as generating a higher spatial resolution of emission inventories of NMVOCs represent an area for future studies on NMVOCs in China.  相似文献   

A New Index Developed for Fast Diagnosis of Meteorological Roles in Ground-Level Ozone Variations     

Weihua CHEN  Weiwen WANG  Shiguo JIA  Jingying MAO  Fenghua YAN  Lianming ZHENG  Yongkang WU  Xingteng ZHANG  Yutong DONG  Lingbin KONG  Buqing ZHONG  Ming CHANG  Min SHAO  Xuemei WANG 《大气科学进展》2022,39(3):403-414

China experienced worsening ground-level ozone(O₂) pollution from 2013 to 2019. In this study, meteorological parameters, including surface temperature(T₂), solar radiation(SW), and wind speed(WS), were classified into two aspects,(1) Photochemical Reaction Condition(PRC = T₂× SW) and(2) Physical Dispersion Capacity(PDC = WS). In this way, a Meteorology Synthetic Index(MSI = PRC/PDC) was developed for the quantification of meteorology-induced ground-level O₂pollution. The positive linear relationship between the 90 th percentile of MDA8(maximum daily 8-h average) O₂concentration and MSI determined that the contribution of meteorological changes to ground-level O-3 varied on a latitudinal gradient, decreasing from ~40% in southern China to 10%–20% in northern China. Favorable photochemical reaction conditions were more important for ground-level O₂pollution. This study proposes a universally applicable index for fast diagnosis of meteorological roles in ground-level O₂variability, which enables the assessment of the observed effects of precursor emissions reductions that can be used for designing future control policies.  相似文献